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Basic Information on Relative Dating
Relative Dating
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Relative dating helps in identying what items are older or younger at an archaeological site.
  Relative Dating only indicates whether something is older or younger than something else, not the actual age.
There are four primary relative dating techniques: Superposition, Cross Dating, Fluorine, and Seriation.
Basic Principles
  There are three major divisions when dating material: chronometric or absolute dating, relative dating, and experimental.
   Relative dating does not give the actual age of a site or artifact, but it does help in identifying what things are older or younger.  The primary techniques utilized for relative dating include: superposition, cross dating, fluorine, and seriation.
  
Superposition is what is commonly used in fieldwork when excavating a site.  The Law of Superposition states that something located above something else is not as old, since the lower item had to have existed before the material above was deposited on it.  In essence, the deeper you go, the further back in time you travel.  Obviously, there are many exceptions to this rule with distrubances.  Human disturbance, rodent disturbance, and environmental impact can all cause a disturbance in superposition.
  
Cross Dating is simply comparing finds to what we know about other sites.  For example, coins, pottery, or other items that are well dated and documented can give a relative date for when it had been deposited.
  
Fluorine dating measures the differences in fluorine content in materials.  Fluorine is a common substance in water, but it varies with location.  Bone absorbs fluorine, and the amount absorbed can be measured.  If two bones are deposited at the same location at relatively the same time, the fluorine content should be nearly the same.  If bone C has less fluorine than bone D, then one can assume that bone C is younger than bone D.  Bone C would have been in the ground and exposed to fluorine in the groundwater for a shorter amount of time than Bone D.  Using fluorine as a relative dating measurement is site specific, as fluorine levels vary with location...and quite likely with time as well.
  Seriation is used to place various sites in time relative to each other.  The idea of popularity or large use comes into play here.  A tool, pottery style, etc. will be introduced, peak, and dwindle out as another item comes into play.  This effect is often called a "battleship curve", which can be seen in graphical depictions.  In essence, as tool A increases in popularity, tool B decreases.  For a similar present day example, think of computers in our day and age.  The introduction of the first Apple computers were in schools everywhere.  New technology caused these early computers to peak and decline, eventually being replaced by newer versions and hardware.  The frequency of these shifts can be graphed and give a relative date of a site or location.
Further Resources:
About Seriation
Application of Relative Dating Techniques
Basic Glossary
Dating Techniques
Dating Techniques in Archaeology
Flourine Dating
Geological Relative Dating Laboratory
Relative Dating
Seriation
Seriation, Stratigraphy, and Index Fossils - The Backbone of Archaeological Dating
   By: Michael O'Brien, Lee Lyman
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Price: $69.50
Fluorine Chemistry for Organic Chemists
   By: Milos Hudlicky
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Price: $59.50
Experimental Methods in Organic Fluorine Chemistry
   By: Tomoya K. & Takashi Y.
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Price: $129.95
Surfaces and Superposition: Field Notes on some Geometrical Excavations
   By: Ernest Adams
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Price: $23.00
Vibration Analysis of Plates by the Superposition Method
   By: Daniel Gorman
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Price: $90.00
Journal of Fluorine Chemistry (Magazine Subscription)
   By: Elsevier Bv
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Price: $224.46  :  1 Year
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