Nuclear Chemistry

 

The following problems are taken from T. L. Brown, H. E. Lemay, B. E. Bursten, & J. R. Burdge, Chemistry: The Central Science, Ninth Edition, Chapter 21.

 

12) Each of the following nuclei undergoes either beta or positron emission. Predict the type of emission for each:

       (a) 6632Ge

       (b) 10545Rh

       (c) iodine-137

       (d) cerium-133

                  

16) In each of the following pairs, which nuclide would you expect to be the more abundant in nature and justify your choices:

      (a) 11548Cd or 11248Cd

      (b) 3013Al or 2713Al

      (c) palladium-106 or palladium-113
             
      (d) xenon-128 or cesium-128

               

26) Write balanced equations for:   

      (a) 23892U(α,n)24194Pu    

      (b) 147N(α,p)178O

      (c) 5926Fe(α,β)6329Cu

      


36) Cobalt-60, which undergoes beta decay, has a half-life of 5.26 yr. 

      (a) How many beta particles are emitted in 45.5 s by a 2.44-mg sample of 60Co?

      (b) What is the activity of the sample in Bq?

           

44) How much energy must be supplied to break a single 21Ne nucleus into separated protons and neutrons if the nucleus has a mass of 20.98846 amu? What is the nuclear binding energy for 1 mol of 21Ne?

       

76) The Sun radiates energy into space at the rate of 3.9 x 1026 J/s.

      (a) Calculate the rate of mass loss from the Sun in kg/s.    

      (b) How does this mass loss arise?

      

      

      

 

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