I. Periodic Properties of the Elements
II. Periodic Properties
A. Related to repeating e- configuration
B. Increase in valence e-
C. Shielding
D. Properties repeat
III. Examples
A. Density
B. Atomic Radius
C. Boiling Point
D. Melting Point
IV. Reaction Tendencies
A. Ionization Energy
B. Electron Affinity
V. Patterns in Size: Atomic Radius
A. Distance from nucleus to outer level
VI. Atomic Radius: Down column
A. Increases
B. Distance inverse to force
C. Full levels shield e- from nucleus
VII. Atomic Radius: Across row
A. Decreases
B. Both p+ and e- increase
C. Increase q direct to force
VIII. Transition Metals
A. Filling d sublevel increases shielding
B. Atomic radius increases
IX. Noble Gas Exception
A. Outer e- on adjacent atoms interact
B. Atom compressed
C. Noble gas outer level full
D. No interaction, no compression
X. Ionic Radius
A. Mimic noble gas configuration
B. Lose e-, greater attraction
C. Gain e-, lower attraction
D. Increase down column
E. Decrease across row
XI. Oxidation Numbers
A. Gain or lose e- to produce noble gas configuration
XII. Groups 1,2,13
A. Matches number of e- in outer level
B. Outer level only s and p
XIII. Groups 3-12
A. Lose outer level e- first
B. d1 to d5: lose e- until d empty
C. d6 to d9: lose e- until d half full
XIV. Group 14
A. Have 4 e-
B. Share e-
XV. Groups 15 to 17
A. Gain e- to fill outer level
B. Oxidation number in number needed to fill level
XVI. Chemical Reactivity
A. Related to gain or loss of electrons
B. Metals: Ionization Energy
C. Non-Metals: Electron Affinity
XVII. Ionization Energy
A. Energy required to remove an electron
XVIII. Factors Affecting Ionization Energy
A. Nuclear charge
B. Radius
C. Shielding effect
D. Sublevel
XIX. First Ionization Energy
A. Increases across row
1. Nuclear charge increases
2. Field Strength increases
B. Decreases down row
1. Radius increases
2. Shielding increases
C. Low for metals, high reactivity
XX. Other Ionization Energies
A. Fewer e-, stronger nuclear pull
B. Atom more stable, need more energy
XXI. An Example: Al
A. 1s22s22p63s23p1
B. 3p1 electron easily removed
C. 3s subshell is full and stable
D. More energy required to remove
XXII. Metals
A. Lose electrons
B. Good conductors
C. Form ionic bonds
XXIII. Alkali Metals
A. Soft, silver/white, good conductors
B. Lose s1 electron
C. Reactivity increases down column
D. React readily with O
E. React violently with H2O
XXIV. Alkaline Earth Metals
A. Too reactive to occur in nature
B. Must lose 2 s electrons, more energy needed
C. More stable than Alkali
D. Denser, harder, higher BP and MP
XXV. Electron Affinity
A. Attraction of an atom for more e-
B. Affected by same factors as Ionization Energy
C. Decreases as e- are gained
XXVI. Electron Affinity: Columns
A. r increases
B. Field strength drops
C. Electron affinity drops
XXVII. Electron Affinity: Rows
A. Charge increases
B. Field strength increases
C. Electron affinity increases
XXVIII. Exceptions to Trend
A. Be: Full 2s sublevel
B. N: ½ full 2p sublevel
C. Ne: full outer level
XXIX. Non-Metals
A. Gain electrons
B. Poor conductors
C. Form covalent bonds
D. Group 14 shares or gains
XXX. Most Reactive
A. Halogens: gain 1
B. Oxygen: gain 2