Subject: Caves: karst formations
The Nation
April 1, 1998

Chemistry at work in bizarre rock formations

      The bizarre, misshapen
      limestone cliffs scattered
      around southern and central
      Thailand form some of the
      country's most spectacular
      scenery. If you've ever stopped
      to take a look at them, you can't
      help but wonder how these
      enchanting towers were formed.

      The answer turns out to be
      almost as interesting as the
      views themselves. For the
      limestone cliffs -- made famous
      the world over by the James
      Bond film The Man with the
      Golden Gun -- are karst
      formations, meaning they are
      sculpted by chemistry rather
      than just erosion.

      Specifically, a rock formation is
      said to be karst if more of its
      material is lost as a result of its
      being dissolved rather than its
      being eroded by the elements,
      according to Dean Smart, a
      cave consultant with the Royal
      Forestry Department (RFD).

      Most limestone formations are
      karst, and most karst formations
      are limestone, but there also
      karst formations made of
      gypsum, rocksalt and even
      quartzite and sandstone, says
      Smart. So karst is really an
      environmental term more than a
      geological term -- the result of a
      complex relationship between
      water, vegetation, soil, rock and
      the atmosphere.

      Limestone mountains are of
      course the remnants of dead
      sea animals, packed together
      under great pressure.
      Limestone is mostly made up of
      calcium carbonate, which
      dissolves in water, but not very
      easily -- unless the water is
      acidic.

      As it happens, much of the
      water found in nature is
      (slightly) acidic. Rainfall picks
      up small amounts of carbon
      dioxide in the atmosphere, and
      larger amounts when it hits the
      ground and mixes with decaying
      matter in the soil, forming
      carbonic acid.

      Limestone dissolves very nicely
      in acidic water, around 15 times
      faster than in normal water.
      That's why you see so many
      small pits (known as ''karren'')
      and pinnacles in the rock on
      limestone mountains. On a
      larger scale, limestone
      formations often feature towers
      and ''dolines'' -- enclosed
      depressions, rather like valleys
      with one or both ends enclosed.

      Another common feature found
      on limestone towers by the sea
      (for instance, in Phang Nga
      Bay) are the indentations found
      at the base of the cliffs. These
      are not the result of battering by
      the waves, explains Smart, nor
      are they strictly caused by rock
      dissolving into the sea, since
      seawater is already saturated
      with limestone.

      Rather, the indentation is a
      result of the mixing of fresh
      (rain) water and seawater.
      ''When they form a mixture of
      about 97 per cent seawater,
      which often occurs as rain runs
      down the cliffs and meets the
      sea, it becomes very
      aggressive, dissolving away the
      base of the towers,'' says
      Smart. ''And the salts in the
      seawater enhance the process,
      acting like a catalyst.''

      What about caves, which seem
      so abundant in limestone
      towers? Limestone actually is
      not very porous, but it does
      have many cracks, he explains.
      Caves are formed as water
      runs into these cracks,
      constantly eating away at the
      rock and widening the channels
      until they intersect.

      The weird chemistry of
      limestone karst formations
      creates other strange features,
      such as the rocky, seemingly
      wind-blown protuberances often
      found at the mouths of caves.
      These are known as
      ''eucladioliths'' and are formed
      because algae tends to grow on
      the side of stalactites which
      face the light. As the algae
      absorbs carbon dioxide from
      water dripping down the
      stalactite, the water
      compensates by depositing
      calcium, and so the eucladiolith
      grows out toward the light --
      almost like living rock.

      The labyrinthine nature of most
      limestone formations also
      makes karst management tricky,
      Smart warns. Dams and roads
      are particularly destructive.

      ''Dams in karst areas cost about
      50 per cent more than in other
      areas because there is lots of
      leakage [through subterranean
      channels],'' he says. ''For the
      Khao Laem Dam in
      Kanchanaburi, they had to build
      a concrete curtain inside the
      mountain to block the leaks. The
      Nam Theun II Dam in Laos is
      also in a limestone karst area.

      ''Karst hydrology is also very
      fragile. It's virtually impossible
      to know which streams produce
      which springs, so construction
      work -- on the Yadana pipeline,
      for instance -- could divert some
      channels, causing some
      streams to completely dry up.''
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