Subject: TBT & sex-shifting shellfish
The Nation
Fri, April 4, 1997

Paint chemical induces sex change in shellfish

   JAMES FAHN

   PATTANI ­ A toxic chemical used to keep ships clean is having a
   bizarre effect on certain species of shellfish ­ it causes them to
   change sex.

   Scientists studying sea snails in the Gulf of Thailand and the Straits
   of Malacca have discovered that where there is heavy shipping traffic,
   including some sites off the Eastern Seaboard, every single female
   found displayed male sexual organs, typically a penis and sperm duct.

   The shellfish have gone ''tomboy" as a result of contamination by a
   chemical called tributyltin (TBT), which creates hormonal imbalances
   in certain snail-like species known as gastropods, said Cornelius
   Swennen, a Dutch marine ecologist. Gastropods include some commonly
   eaten species, such as Babylonia (known in Thailand as hoy khao heuor
   hoy roy ru).

   TBT is an anti-fouling agent, an ingredient in the paints used on
   ships to prevent barnacles and other marine species from sticking to
   hulls, but also leaks into the sea and damages shellfish populations.

   The tin-based chemical is carefully controlled in developed countries
   ­ small ships, such as yachts, are banned from using it ­ but not in
   Southeast Asia, Swennen said.

   The impact of TBT on humans is not known, he added. But a paper
   written by Swennen and his colleagues in the scientific journal
   Wallaceana states that ''its use on ships must be severely reduced in
   the interest of public health and that of the marine environment".

   In theory, humans who eat TBT-contaminated seafood could also be
   subject to hormonal imbalances. But nobody has ever actually seen such
   effects in people and ''a human would have to eat an awful lot of
   contaminated seafood to be affected".

   The scientist said he is greatly concerned over the marine ecosystem,
   however, as the hoy tom (''tomboy shellfish") phenomenon ­ known in
   more formal circles as imposex ­ is irreversible and prevents
   reproduction in affected species, causing shellfish populations to
   drop drastically.

   ''TBT is influencing non-targeted areas. It leaks out from the paint
   on ships' hulls and basically kills all the shellfish larvae in the
   area, including crab and lobster," explained Swennen, who works out of
   Prince of Songkhla University (PSU) in Pattani.

   The affects of TBT have been well-documented in Europe, North America
   and Japan since the late 1960s, when the anti-fouling agent was first
   used. It has caused significant damage to commonly eaten species, such
   as oysters (hoy nang rom) and mussels (hoy malaeng phu).

   But while TBT has an impact on all types of shellfish, and also
   contaminates fish. Swennen said it was found to have a particularly
   disturbing impact on gastropods, inducing females to develop male
   sexual organs in the form of penis-like appendages.

   In fact, the relationship between TBT and the imposex phenomenon has
   become so well-understood that gastropods are now considered a
   bio-indicator for contamination by the anti-fouling agent: scientists
   judge the level of pollution by seeing how many of the shellfish
   display penises and vas deferentia (sperm ducts).

   But it has only recently been shown that the impact of TBT is felt out
   at sea and not simply close to shore. Furthermore, most studies have
   been carried out in temperate or sub-tropical waters.

   So Swennen teamed up with PSU lecturer Nukul Ruttanadakul and Suraphol
   Ardseungnern of Mahidol University to check imposex levels in the
   inner Gulf of Thailand and around Pattani. Malaysian and Singaporean
   researchers helped look for sex-shifting shellfish in the Straits of
   Malacca.

   ''The results show that TBT pollution is now a global problem,"
   Swennen said. ''The contamination levels depend on the amount of
   shipping traffic rather than the size of the boat or the depth of the
   sea. Gastropods collecting near major shipping lanes all had imposex
   characteristics."

   The greatest contamination areas found in Thai waters were off Chon
   Buri, where imposex incidences reached 100 per cent at a couple of
   sites. Meanwhile, in the western part of the inner gulf, off
   Phetchaburi, no transexual shellfish were found.

   Imposex levels were also found to be quite high in Pattani Bay (86 per
   cent), off the northern shore of Singapore (88 per cent) and in the
   Straits of Malacca, due west of Singapore (100 per cent).

   Swennen said he tried to contact each country's representative to the
   Marpol Convention, which is supposed to oversee marine pollution
   issues. Countries that are party to Marpol, including Thailand, are
   supposed to ban the use of TBT on ships smaller than 25 metres and set
   controls on leaching rates from marine paints used on larger ships.

   ''The Singaporean official acknowledged that it is a major problem,
   but he said they are under a lot of pressure from the [shipping and
   TBT manufacturing] industry," the Dutch researcher said. ''The Thai
   representative didn't respond."

   Harbour Department officials are supposed to look after Thailand's
   obligations under the Marpol Convention, but a source from the agency
   said that no action has been taken in regards to TBT in Thailand.

   ''At a recent Marpol meeting in London, some governments asked for a
   tin-free alternative to TBT that would be less damaging to shellfish,"
   said the Harbour Department official who asked not to be named. ''But
   the European Chemical Manufacturers Federation said there is no
   alternative available that works with such efficiency."

   The source said that a lot of the smaller fishing boats in Thailand
   use marine paints that contain copper-based anti-fouling agents
   because they are cheaper. But these chemicals also damage crustaceans
   such as crabs, shrimp and lobster, the official said, and will affect
   the health of people who eat the contaminated seafood.
  1